The Messenger of Allah said: "Whoever catches one Rak'ah of the 'Asr before the sun sets, then he has caught it, and whoever catches one Rak'ah of the Subh before the sun rises, then he has caught it."
Reference: Sunan Ibn Majah 699 In-book : Book 2, Hadith 33 English translation : Vol. 1, Book 2, Hadith 699
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