"Allah's Messenger would pray four (Rak'ah) after the Zawal of the sun before Az-Zuhr. He said: 'It is an hour in which the gates of the heavens are opened, and I love that a righteous deed should be raised up for me in it.'"
Reference: Jami` at-Tirmidhi 478 In-book : Book 3, Hadith 26 English translation : Vol. 1, Book 3, Hadith 478
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