Between every two calls (Adhan and Iqama) there is a Salat (prayer) (that is optional) for the one who wants to offer it.
باب بَيْنَ كُلِّ أَذَانَيْنِ صَلاَةٌ لِمَنْ شَاءَ
6842
Sahih Bukhari
Sahih
حَدَّثَنَا قُتَيْبَةُ بْنُ سَعِيدٍ، حَدَّثَنَا لَيْثٌ، عَنْ نَافِعٍ، عَنِ ابْنِ عُمَرَ ـ رضى الله عنهما ـ أَنَّهُ سَمِعَ رَسُولَ اللَّهِ صلى الله عليه وسلم وَهْوَ مُسْتَقْبِلٌ الْمَشْرِقَ يَقُولُ أَلاَ إِنَّ الْفِتْنَةَ هَا هُنَا مِنْ حَيْثُ يَطْلُعُ قَرْنُ الشَّيْطَانِ "
Narrated Ibn `Umar:
I heard Allah's Messenger (ﷺ) while he was facing the East, saying, "Verily! Afflictions are there, from where the side of the head of Satan comes out."
Reference: Sahih al-Bukhari 7093 In-book : Book 92, Hadith 44 USC-MSA web (English) : Vol. 9, Book 88, Hadith 213 (deprecated)
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